|
| COMMON NAME | : | |
| SYMBOL | : | |
| FORMULA | : | C23H40O4 MOL.WT (average) : 380.561 |
| BIOLOGICAL ACTIVITY |
| PHYSICAL AND CHEMICAL PROPERTIES |
| MELTING POINT | : | 22S: 138.5-140, 22R: 229-230 (Ref. 0446) |
| BOILING POINT | : | |
| REFRACTIVE INDEX | : | |
| OPTICAL ROTATION | : | 22S: [a]D=+8.2, 22R: [a]D=+0.7 (Ref. 0446) |
| DENSITY | : | |
| SOLUBILITY | : | |
| SPECTRAL DATA |
| UV SPECTRA | : | |
| IR SPECTRA | : | 3400 cm-1 (KBr disc) (Ref. 0446) |
| NMR SPECTRA | : | 22S: 0.71(s,3H,18-CH3), 0.97(s,3H,19-CH3), 1.24(d, J=6Hz, 3H,21-CH3), 3.4-4.4(m,5H, CH-OH's); 22R:0.77(s,3H,18-CH3), 0.97(s,3H,19-CH3), 1.21(d, J=6Hz, 3H,21-CH3), 3.4-4.4(m,5H, CH-OH's)(Ref. 0446) |
| MASS SPECTRA | : | m/z 565,475,385,345,295,255 (as TMS derivative) (Ref. 0446) |
| OTHER SPECTRA | : | |
| CHROMATOGRAM DATA |
| SOURCE |
| CHEMICAL SYNTHESIS |
| METABOLISM |
| GENETIC INFORMATION |
| NOTE |
| REFERENCES |
| AUTHOR | : | Kihira,K.,Morioka,Y., and Hoshita,T. |
| TITLE | : | Synthesis of (22R and 22S)-3a,7a,22-trihydroxy-5b-cholan-24-oic acids and structure of haemulcholic acid, a unique bile acid isolated from fish bile. PubMed ID:7320628 |
| JOURNAL | : | J.Lipid Res. |
| VOL | : | 22 PAGE : 1181 -1187 (1981) |