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Fatty acid


DATA No : DFA8090 INFORMANT : Tetsuyuki Kobayashi

NAME : 7-[3,5-Epidioxy-2-(2-Octenyl)Cyclopentyl]-5-Hydroperoxy-6-Heptenoic Acid/7-[3,5-Epidioxy-2-(2-Octenyl)Cyclopentyl]-5-Hydroperoxy-6-Heptenoate

COMMON NAME:
SYMBOL:
FORMULA: C20H32O6 MOL.WT (average) : 368.464


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BIOLOGICAL ACTIVITY

PHYSICAL AND CHEMICAL PROPERTIES
MELTING POINT:

BOILING POINT:

REFRACTIVE INDEX:

OPTICAL ROTATION:

DENSITY:

SOLUBILITY:
SPECTRAL DATA
UV SPECTRA:

IR SPECTRA:

NMR SPECTRA:

MASS SPECTRA:GC-EI-MS(Me-ester; after reduction and TMS)(Ref. 8080): m/e=569[M-CH3]; 494[M-HOTMS]; 483[M-(CH2)3COOCH3]; 404[M-2xHOTMS]; 378[494-SMTO=CHCH2]; 367[M-SMTOCH=CHCH=OTMS]; 203[SMTO=CH(CH2)3COOCH3]; 191[SMTO=CHOTMS]

OTHER SPECTRA:
CHROMATOGRAM DATA

SOURCE
Oxidation of arachidonic acid in the presence of hemoglobin, mioglobin(Ref. 8080) or Fe(III)- ascorbic acid(Ref. 8097).
CHEMICAL SYNTHESIS

METABOLISM

GENETIC INFORMATION

NOTE

REFERENCES
[8080]
AUTHOR:Terao, J., and Matsushita, S.
TITLE:Analysis of Hemoprotein Catalyzed Peroxidation Products of Arachidonic Acid by Gas Chromatography- Mass Spectrometry
JOURNAL:Agric. Biol. Chem.
VOL:45 PAGE : 595 -599 (1981)
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[8097]
AUTHOR:Yamagata, S., Murakami, H., Terao, J., and Matsushita, S.
TITLE:Nonenzymatic Oxidation Products of Methyl Arachidonate
JOURNAL:Agric. Biol. Chem.
VOL:47 PAGE : 2791 -2799 (1983)
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Last updated June 19, 2007. Copyright © 1989-2007 Japanese Conference on the Biochemistry of Lipids (JCBL). All rights reserved.