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Fatty acid


DATA No : DFA8093 INFORMANT : Tetsuyuki Kobayashi

NAME : Methyl 6,8-Epidioxy-5,15-Dihydroperoxy-9,11,13-Eicosatrienoate

COMMON NAME:
SYMBOL:
FORMULA: C21H34O8 MOL.WT (average) : 414.490


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BIOLOGICAL ACTIVITY

PHYSICAL AND CHEMICAL PROPERTIES
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SPECTRAL DATA
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IR SPECTRA:

NMR SPECTRA:

MASS SPECTRA:GC-EI-MS(after reduction, hydrogenation and TMS-derivatization)(Ref. 8097): m/e=517[M-(CH2)4CH3-HOTMS]; 427[M-(CH2)4CH3-2xHOTMS]; 385[M-SMTO=CH(CH2)3COOCH3-HOTMS]; 359[SMTO=CH(CH2)6CH(OTMS)(CH2)4CH3]; 337[M-(CH2)4CH3-3xHOTMS]

OTHER SPECTRA:
CHROMATOGRAM DATA

SOURCE
In degradation products of 15-hydroperoxides of arachidonic acid in the presence of Fe(III)-ascorbic acid. Oxidation of arachidonic acid in the presence of Fe(III)-ascorbic acid(Ref. 8097).
CHEMICAL SYNTHESIS

METABOLISM

GENETIC INFORMATION

NOTE

REFERENCES
[8097]
AUTHOR:Yamagata, S., Murakami, H., Terao, J., and Matsushita, S.
TITLE:Nonenzymatic Oxidation Products of Methyl Arachidonate
JOURNAL:Agric. Biol. Chem.
VOL:47 PAGE : 2791 -2799 (1983)
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Last updated June 19, 2007. Copyright © 1989-2007 Japanese Conference on the Biochemistry of Lipids (JCBL). All rights reserved.