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Fatty acid


DATA No : DFA8094 INFORMANT : Tetsuyuki Kobayashi

NAME : Methyl 6,8,9,11-Bisepidioxy-5-Hydroperoxy-12,14-Eicosadienoate

COMMON NAME:
SYMBOL:
FORMULA: C21H34O8 MOL.WT (average) : 414.490


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BIOLOGICAL ACTIVITY

PHYSICAL AND CHEMICAL PROPERTIES
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SPECTRAL DATA
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NMR SPECTRA:

MASS SPECTRA:GC-EI-MS(after reduction, hydrogenation and TMS-derivatization)<<>>: m/e=473[M-SMTO=CH(CH2)3COOCH3-HOTMS]; 383[M-SMTO=CH(CH2)3COOCH3-2xHOTMS]; 331[SMTO=CHCH2CH(OTMS)CH(OTMS)(CH2)3COOCH3-HOTMS]; 241[SMTO=CHCH2CH(OTMS)CH(OTMS)(CH2)3COOCH3-2xHOTMS]

OTHER SPECTRA:
CHROMATOGRAM DATA

SOURCE
In degradation products of 11-hydroperoxides of arachidonic acid in the presence of Fe(III)-ascorbic acid.
CHEMICAL SYNTHESIS

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REFERENCES

Last updated June 19, 2007. Copyright © 1989-2007 Japanese Conference on the Biochemistry of Lipids (JCBL). All rights reserved.