Back to HOME

Fatty acid


DATA No : DFA8097 INFORMANT : Tetsuyuki Kobayashi

NAME : Methyl 6-Hydroperoxy-4,8,11,14,17-Icosapentaenoate

COMMON NAME:
SYMBOL:
FORMULA: C21H32O4 MOL.WT (average) : 348.476


Download ChemDraw structure data
Download Mol format file
BIOLOGICAL ACTIVITY

PHYSICAL AND CHEMICAL PROPERTIES
MELTING POINT:

BOILING POINT:

REFRACTIVE INDEX:

OPTICAL ROTATION:

DENSITY:

SOLUBILITY:
SPECTRAL DATA
UV SPECTRA:

IR SPECTRA:OOH group: 3400cm-1 (Ref. 8109)

NMR SPECTRA:1H-NMR(Ref. 8109): OOH proton: 8.5ppm

MASS SPECTRA:GC-EI-MS(after reduction and TMS-derivatization)(Ref. 8109): m/e=404[M]; 389[M-CH3] 314[M-HOTMS], GC-EI-MS(after reduction, hydrogenation, and TMS-derivatization)(Ref. 8109): m/e=399[M-CH3]; 383[M-OCH3]; 367[399-CH3OH]; 299[SMTO=CH(CH2)13CH3]

OTHER SPECTRA:
CHROMATOGRAM DATA

SOURCE
Oxidation of icosapentaenoate by singlet-oxygen(Ref. 8109).
CHEMICAL SYNTHESIS

METABOLISM

GENETIC INFORMATION

NOTE

REFERENCES
[8109]
AUTHOR:Yamauchi, R., Yamada, T., Kato, K., and Ueno, Y.
TITLE:Monohydroperoxides Formed by Autoxidation and Photosensitized Oxidation of Methyl Eicosapentaenoate
JOURNAL:Agric. Biol. Chem.
VOL:47 PAGE : 2897 -2902 (1983)
[TOP]

Last updated June 19, 2007. Copyright © 1989-2007 Japanese Conference on the Biochemistry of Lipids (JCBL). All rights reserved.